Study of the oxidation process of bismuth nanoparticles using NaClO.

Bismuth nanoparticles (NPs) colloids synthesized in deionized water by laser ablation of solids in liquids technique (LASL) were oxidized using NaClO solutions at different concentrations. Oxidized nanomaterials were characterized using several techniques. The crystalline phases of the bismuth compound were determined using Raman microspectroscopy, and the crystallographic structure was identified by x-ray diffraction (XRD). The size and morphology of the obtained nanomaterials were studied by transmission electron microscopy (TEM). The chemical states were determined using x-ray photoelectron spectroscopy (XPS), and the optical properties of the colloids were characterized by UV-vis spectroscopy. The absorption spectra were analyzed using the Tauc method to determine the band gaps of the obtained nanomaterials. Our results showed morphological changes, starting from small nanoparticles to nanosheets and a mixture of nanosheets with hollow nanoparticles. Two kinds of nanomaterials were found depending on the NaClO solution concentration: Bi2O2CO3single phase and a mixture ofδ-Bi2O3and Bi2O2CO3. Some samples were tested as photocatalysts and showed good performance in the degradation of methylene blue in solution. To the best of our knowledge, this is the first study on the oxidation process of bismuth colloidal nanoparticles at room temperature.

Pump-probe imaging of nanosecond laser-induced bubbles in agar gel.

In this paper we show results of Nd:YAG laser-induced bubbles formed in a one millimeter thick agar gel slab. The nine nanosecond duration pulse with a wave length of 532 nm was tightly focused inside the bulk of the gel sample. We present for the first time a pump-probe laser-flash shadowgraphy system that uses two electronically delayed Nd:YAG lasers to image the the bubble formation and shock wave fronts with nanosecond temporal resolution and up to nine seconds of temporal range. The shock waves generated by the laser are shown to begin at an earlier times within the laser pulse as the pulse energy increases. The shock wave velocity is used to infer a shocked to unshocked material pressure difference of up to 500 MPa. The bubble created settles to a quasi-stable size that has a linear relation to the maximum bubble size. The energy stored in the bubble is shown to increase nonlinearly with applied laser energy, and corresponds in form to the energy transmission in the agar gel. We show that the interaction is highly nonlinear, and most likely is plasma-mediated.

Self-starting Nd:YAG holographic laser oscillator with a thermal grating.

Self-starting operation of a self-conjugating loop oscillator is achieved, for the first time to our knowledge, by use of an optically induced thermal hologram in a nonsaturable absorbing medium. Self-Q-switched single-longitudinal-mode pulses of 12-ns duration are obtained in a near-diffraction-limited spatial mode and with an output energy of >250 mJ . Good correction of intracavity phase distortions is obtained, as well as good extraction efficiency in the laser mode volume. It is shown that one has to set an additional nonreciprocal phase-shift element in the loop to ensure resonant operation of the system.

Experimental investigation of vector phase conjugation in Nd(3+):YAG.

We present a study of vector phase conjugation based on degenerate four-wave mixing in inverted Nd:YAG. The results demonstrate polarization correction for weak probe strength, with near-unity fidelity for polarization compensation of the returning conjugate. As the probe strength is increased, the fidelity of the polarization state of the conjugate is seen to deteriorate to an average value of 92% when the probe is strongly saturating and is several times stronger than the pump beams. We also show that, for strong probe strengths, an individual transmission grating or reflection grating is more efficient than when both gratings are present.

Phase conjugation in amorphous selenium thin films.

We report phase conjugation in amorphous selenium thin films with a 25-mW He-Ne laser. The phase-conjugate signal exhibits a maximum efficiency of 18%. Gratings were recorded with spatial frequencies of 275 lines/mm. We have performed micro Raman spectroscopy measurements between and on the lines that form the grating, and the results reveal the presence of amorphous selenium only. Scanning electron microscopy together with profilometry measurements indicate induced variations of the film thickness. However, this relief does not seem sufficient to explain the observed effects.

Laser-induced diffraction patterns in germanium diselenide amorphous films.

We report the characterization of changes produced on germanium diselenide amorphous semiconductor thin films by a focused He-Ne laser beam. The diffraction pattern produced by the laser spot on the sample is studied as a function of the intensity and the irradiation time. At low intensities the state of polarization of the incident beam generates an asymmetry in the induced diffraction pattern. Moreover, if the polarization of the incident beam is rotated, the corresponding asymmetry rotates as well. These results show the difference between thermal and electromagnetic effects on the material. This system may be used as a high density recording medium.